dc.contributor.author | Filippova, Liudmila | |
dc.contributor.author | Stenstrøm, Yngve H. | |
dc.contributor.author | Hansen, Trond Vidar | |
dc.date.accessioned | 2015-07-28T09:03:02Z | |
dc.date.accessioned | 2015-08-17T07:37:27Z | |
dc.date.available | 2015-07-28T09:03:02Z | |
dc.date.available | 2015-08-17T07:37:27Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | Molecules 2015, 20:6224-6236 | nb_NO |
dc.identifier.issn | 1420-3049 | |
dc.identifier.uri | http://hdl.handle.net/11250/297114 | |
dc.description | - | nb_NO |
dc.description.abstract | A novel C1-symmetric dinitrogen ligand was synthesized in high yield from commercially available (1R,2R,3R,5S)-(−)-isopinocampheylamine and 1-methyl-2- imidazolecarboxaldehyde. In combination with Cu(OAc)2∙H2O, this new ligand promote the reaction between nitromethane and aliphatic aldehydes with high yields (up to 97%) and moderate enantioselectivities (up to 67% ee). The reactions with benzaldehyde required prolonged reaction time that resulted in diminished yields, but accompanied with ee-values in the 55%–76% range. | nb_NO |
dc.language.iso | eng | nb_NO |
dc.relation.uri | http://www.mdpi.com/1420-3049/20/4/6224 | |
dc.rights | Navngivelse 3.0 Norge | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/no/ | * |
dc.title | Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C1-Symmetric Aminopinane-Derived Ligand | nb_NO |
dc.type | Journal article | nb_NO |
dc.type | Peer reviewed | nb_NO |
dc.date.updated | 2015-07-28T09:03:02Z | |
dc.identifier.doi | 10.3390/molecules20046224 | |
dc.identifier.cristin | 1237188 | |